Vacancy-driven magnetocaloric effect in Prussian blue analogues
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چکیده
منابع مشابه
Vacancy-driven magnetocaloric effect in Prussian blue analogues
We experimentally show that the magnetocaloric properties of molecule-based Prussian blue analogues can be adjusted by controlling during the synthesis the amount of intrinsic vacancies. For CsxNi II 4 [Cr (CN)6](8+x)/3, we find indeed that the ferromagnetic phase transition induces significantly large magnetic entropy changes, whose maxima shift from∼ 68 K to∼ 95 K by varying the number of [Cr...
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ژورنال
عنوان ژورنال: Journal of Magnetism and Magnetic Materials
سال: 2007
ISSN: 0304-8853
DOI: 10.1016/j.jmmm.2007.03.038